This corresponds well with the solubility limit of In in PbTe. We have also tested In doping into interstitial sites of the PbTe lattice. At the most likely (0.25, 0.25, 0.25) interstitial site, the insertion energy comes to be 0.068 eV. From these energy calculations, as well as from our X-ray measurement, we can conclude that In doping, at our level of 1.5 at%, allows substitution on the Pb site. Our conclusion is consistent with a previous first principle calculation of aluminum (Al) doping on PbSe [25], which also concluded that Al atoms prefer to ARS-1620 replace Pb
rather than to take interstitial sites. The reported band structure and density of states (DOS) calculation showed that upon low-level doping of Al, the enhanced density of states of PbSe near the Fermi energy is responsible for enhanced carrier density, which leads check details to higher conductivity. Since In doping to our PbTe sample allows substitution on the Pb site, we expect a similar effect on electronic properties of our PbTe samples upon doping. To further investigate the incorporation of indium into the PbTe matrix, the
LIBS analyses were performed on the undoped (PbTe-2) and two indium-doped (In01PbTe Captisol manufacturer and In02PbTe) samples, respectively. LIBS emission spectra were obtained in the wavelength range of 200 to 1,040 nm. The presence of indium in the samples In01PbTe and In02PbTe was confirmed by the detection of nine different emission lines at 256.0, 271.0, 275.4, 293.3, 303.9, 325.6, 410.2, 451.1, and 465.6 nm. Figure 3a shows typical spectra and some emission peaks detected for In and Pb on sample In02PbTe. Tellurium (Te) peaks were not detected due to the very high ionizing potential of Te which was beyond the operational range of the LIBS instrument. LIBS spectra also show some prominent impurity peaks of magnesium (Mg) which may have come
from some trace amount of metal impurities (approximately 0.2%) present in the precursor materials (Te) used in the synthesis. Figure 3a is the LIBS emission spectra of In02PbTe for the selected range from 300 to 466 nm which shows the presence of atomic indium peaks at different wavelengths Metalloexopeptidase from 256.0 to 466 nm. Figure 3b,c shows the LIBS indium emission lines at 410 and 325 nm for undoped PbTe (blue), In01PbTe (green), and In02PbTe (red), respectively. Undoped PbTe does not show any indium peak at both the wavelengths, indicating the absence of indium. However, In01PbTe and In02PbTe samples show the presence of indium lines at 410 and 325 nm with almost linear increase in intensity with increasing indium content. The presence of multiple indium emission lines and linear increase in intensity from the samples In01PbTe and In02PbTe confirm the incorporation of indium into the PbTe matrix in doped samples. From the result of LIBS analyses, first principal energy calculations, and X-ray measurement, we can conclude that at the level of 1.
Related posts:
- The inset shows the corresponding plots of (αhν)1/2 as a function
- The overall decrease of the emission intensity is consistent with
- It is clear that the most probable diameter is in the range from
- The lower limit of quantification was 0 200 ng/mL The between- <
- In order to avoid the possibility of over-nitridation, a lower am